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Any withdrawal from your investment bond may create what is called a 'chargeable event'. When a chargeable event happens, this may create what is called a 'chargeable event gain', on which you may have to pay Income Tax. It may also affect your entitlement to personal allowance.
A liability to Income Tax at the marginal rate (the difference between the basic rate and your highest rate) may be due if a gain is made when a chargeable event occurs.